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titanium tetrafluoride : ウィキペディア英語版
titanium tetrafluoride

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Titanium(IV) fluoride is the inorganic compound with the formula TiF4. It is a white hygroscopic solid. In contrast to the other halides of titanium, it adopts a polymeric structure consisting of octahedral Ti centres.
==Preparation==
The traditional method involves treatment of titanium tetrachloride with excess hydrogen fluoride, and purification by sublimation:〔Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 200.〕
:TiCl4 + 4 HF → TiF4 + 4 HCl

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